Nato a Roma nel 1964, è un attore e doppiatore italiano. Il suo esordio artistico come doppiatore è con Chunk, protagonista del film Goonies. Debutta sul grande schermo con il film Sposerò Simon Le Bon, al fianco di Gianmarco Tognazzi ed è è coprotagonista nel film L'italiano (2002), diretto da Ennio De Dominicis. Nel 2004 è nel cast del kolossal La passione di Cristo, diretto da Mel Gibson, nel ruolo di Giuda Iscariota, mentre nel 2005 recita nel film Concorso di colpa (2005) di Claudio Fragasso. Ha recitato in fiction di successo come San Pietro (2005), regia di Giulio Base, Sospetti 3, diretta da Gianni Lepre e Squadra Antimafia Palermo oggi 4 (2012), con la regia di Beniamino Catena. Luca è figlio di Oreste Lionello.
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